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THE thickening of oxide or other films on metals according to the parabolic equation y 2= K 1 t + K 2 (where y is the film thickness at time t and all K's are constants) is generally attributed to lattice-defects, K 1 being related to the electrical constants of the film substance by Wagner's equations 1. Logarithmic thickening (y = K 3 log ( K 4 t + K 5) is, in my view 2, associated with discrete mechanical breakdowns caused by the strains arising from the volume increase accompanying oxidation; evidence of such strains is provided by the wrinkling observed during film-stripping 3. Wagner, C., Z. Chem., (B), 21, 25 (1933); Trans. Faraday Soc., 34, 851 (1938). P. Autodesk 3ds max design 2015 x64 rusifikator. , and Price, L.
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Faraday Soc, 34, 867 (1938). Faraday Soc., 35, 1175 (1939); 36, 472 (1940). Soc., 83, 337 (1943); Trans. Faraday Soc., 41, 365 (1945).
R., and Stockdale, J., J. Soc., 2651 (1929). For analysis, see Stuart, N., and Evans, U. Iron and Steel Inst., 147, 131P (1943). B., and Ward, E. Ind., 53, 382T (1934). Huddle has improved the machine, adding an adjustable counterpoise so that the load is read directly from the weights in the pan.
J., Akeroyd, E. I., and Stroud, E. Met., 65, 301 (1939). Faraday Soc., 19, 839 (1923); 23, 113 (1927).
B., and Evans, U. Faraday Soc., 31, 527 (1935). B., and Brown, R. Chem., 29, 1087 (1937).
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